Secondary battery electrode plate and secondary battery using same

ABSTRACT

A secondary battery with a positive electrode plate having a metallic positive electrode core body and positive electrode active material layers formed on both surfaces of the positive electrode core body. The positive electrode core body has an active material layer-free region in which the positive electrode active material layers are not formed on the surface of the positive electrode core body, wherein a first protrusion protruding in the thickness direction of the positive electrode core body from one surface of the positive electrode core body is formed at the end of the active material layer-free region, positive electrode protection layers are formed in a portion adjacent to the positive electrode active material layers on one surface of the positive electrode core body in the active material layer-free region, and the protrusion height T 1  of the first protrusion is less than the thickness T 2  of the positive electrode protection layer.

TECHNICAL FIELD

The present invention relates to an electrode plate for a secondary battery and a secondary battery using the same.

BACKGROUND ART

Secondary batteries, such as alkaline secondary batteries and non-aqueous electrolyte secondary batteries, are used in the driving power sources of electric vehicles (EV) and hybrid electric vehicles (HEV or PHEV).

These secondary batteries contain an electrode assembly consisting of a positive electrode plate, a negative electrode plate, and a separator together with an electrolyte in a battery case. The battery case is composed of an exterior body having an opening and a sealing plate that seals the opening of the exterior body. A positive electrode terminal and a negative electrode terminal are attached to the sealing plate. The positive electrode terminal is electrically connected to the positive electrode plate with a positive electrode current collector therebetween, and the negative electrode terminal is electrically connected to the negative electrode plate with a negative electrode current collector therebetween.

As such a secondary battery, a secondary battery has been proposed in which a positive electrode tab group consisting of a plurality of positive electrode tabs and a negative electrode tab group consisting of a plurality of negative electrode tabs are provided at the end of the electrode assembly adjacent to the sealing plate (see Patent Literature 1).

CITATION LIST Patent Literature

-   PATENT LITERATURE 1: Japanese Unexamined Patent Application     Publication No. 2016-115409

SUMMARY

It is an advantage of the present invention is to provide a highly reliable secondary battery in which short circuits between the positive electrode plate and the negative electrode plate are suppressed.

A secondary battery electrode plate according to one aspect of the present invention has a metal core body and an active material layer on both sides of the core body, wherein the core body has an active material layer-free region in which the active material layer is not formed on a surface of the core body, a first protrusion that protrudes from one side of the core body in the direction of the thickness of the core body is formed at an end of the active material layer-free region, on the one side of the core body of the active material layer-free region, a protective layer is formed in a portion adjacent to the active material layer, and the protrusion height of the first protrusion is smaller than the thickness of the protective layer.

A secondary battery according to one aspect of the present invention includes the electrode plate and another electrode plate having a polarity different from that of the electrode plate.

According to the present invention, a highly reliable secondary battery can be provided.

BRIEF DESCRIPTION OF DRAWINGS

FIG. 1 is a perspective view of a secondary battery according to an embodiment.

FIG. 2 is a cross-sectional view taken along line II-II in FIG. 1.

FIG. 3A is a plan view of a positive electrode original plate. FIG. 3B is a plan view of the positive electrode original plate with tabs already formed. FIG. 3C is a plan view of the positive electrode plate.

FIG. 4 is a cross-sectional view taken along line IV-IV in FIG. 3C.

FIG. 5A is a plan view of a negative electrode original plate. FIG. 5B is a plan view of the negative electrode original plate with tabs already formed. FIG. 5C is a plan view of the negative electrode plate.

FIG. 6 is a plan view of an electrode assembly according to the embodiment.

FIG. 7 is a diagram showing a state in which a positive electrode tab group is connected to a second positive electrode current collector and a negative electrode tab group is connected to a second negative electrode current collector.

FIG. 8 is a diagram showing a surface of a sealing plate adjacent to the electrode assembly after the first positive electrode current collector and the first negative electrode current collector are attached to the sealing plate.

FIG. 9 is a diagram showing a surface of the sealing plate adjacent to the electrode assembly after the second positive electrode current collector is attached to the first positive electrode current collector and the second negative electrode current collector is attached to the first negative electrode current collector.

DESCRIPTION OF EMBODIMENTS

The configuration of a square secondary battery 20 as a secondary battery according to the embodiment will be described below. Note that the present invention is not limited to the following embodiments.

As shown in FIGS. 1 and 2, the square secondary battery 20 comprises a battery case 100 consisting of a bottomed hollow rectangular cylindrical exterior body 1 having an opening and a sealing plate 2 for sealing the opening of the square exterior body 1. The square exterior body 1 and the sealing plate 2 are preferably made of metal. An electrode assembly 3 including a positive electrode plate and a negative electrode plate is accommodated in the square exterior body 1 together with an electrolyte.

At the end of the electrode assembly 3 adjacent to the sealing plate 2, a positive electrode tab group 40A composed of a plurality of positive electrode tabs 40 and a negative electrode tab group 50A composed of a plurality of negative electrode tabs 50 are provided. The positive electrode tab group 40A is electrically connected to a positive electrode terminal 7 via a second positive electrode current collector 6 b and a first positive electrode current collector 6 a. The negative electrode tab group 50A is electrically connected to a negative electrode terminal 9 via a second negative electrode current collector 8 b and a first negative electrode current collector 8 a. The first positive electrode current collector 6 a and the second positive electrode current collector 6 b constitute a positive electrode current collector 6. Note that the positive electrode current collector 6 may be used as one component. The first negative electrode current collector 8 a and the second negative electrode current collector 8 b constitute a negative electrode current collector 8. Note that the negative electrode current collector 8 may be used as one component.

The first positive electrode current collector 6 a, the second positive electrode current collector 6 b, and the positive electrode terminal 7 are preferably made of metal, and more preferably made of aluminum or an aluminum alloy. A resin external insulating member 10 is disposed between the positive electrode terminal 7 and the sealing plate 2. A resin internal insulating member 11 is disposed between the first positive electrode current collector 6 a and the second positive electrode current collector 6 b, and the sealing plate 2.

The first negative electrode current collector 8 a, the second negative electrode current collector 8 b, and the negative electrode terminal 9 are preferably made of metal, more preferably copper or a copper alloy. The negative electrode terminal 9 preferably has a portion of aluminum or an aluminum alloy and a portion of copper or a copper alloy. In this case, the portion of copper or a copper alloy is preferably connected to the first negative electrode current collector 8 a so that the portion of aluminum or an aluminum alloy protrudes to the outside of the sealing plate 2. A resin external insulating member 12 is disposed between the negative electrode terminal 9 and the sealing plate 2. A resin internal insulating member 13 is disposed between the first negative electrode current collector 8 a and the second negative electrode current collector 8 b, and the sealing plate 2.

An electrode assembly holder 14 composed of a resin sheet, which is made of resin, is disposed between the electrode assembly 3 and the square exterior body 1. The electrode assembly holder 14 is preferably formed by bending a resin insulating sheet into a bag shape or a box shape. The sealing plate 2 has an electrolytic solution injection hole 15, and the electrolytic solution injection hole 15 is sealed by a sealing member 16. The sealing plate 2 has a gas discharge valve 17 that breaks when the pressure inside the battery case 100 exceeds a predetermined value to discharge the gas inside the battery case 100 to the outside of the battery case 100.

A method of manufacturing the square secondary battery 20 and the details of each component will now be explained.

[Positive Electrode Plate]

The method of manufacturing the positive electrode plate will be first explained.

[Preparation of Positive Electrode Active Material Layer Slurry]

Lithium nickel manganese cobalt oxide as a positive electrode active material, polyvinylidene fluoride (PVdF) as a binder, a carbon material as a conductive agent, and N-methyl-2-pyrrolidone (NMP) as a dispersion medium are mixed so that the lithium nickel manganese cobalt oxide:PVdF:carbon material mass ratio becomes 97.5:1:1.5, thereby preparing a positive electrode active material layer slurry.

[Preparation of Positive Electrode Protective Layer Slurry]

Alumina powder, a carbon material as a conductive material, polyvinylidene fluoride (PVdF) as a binder, and N-methyl-2-pyrrolidone (NMP) as a dispersion medium are mixed so that the alumina powder:carbon material:PVdF mass ratio becomes 83:3:14, thereby preparing a protective layer slurry.

[Formation of Positive Electrode Active Material Layer and Positive Electrode Protective Layer]

The positive electrode active material layer slurry and the positive electrode protective layer slurry prepared by the aforementioned method are applied to both sides of an aluminum foil as a positive electrode core body having a thickness of 15 μm with a die coater. At this time, the positive electrode active material layer slurry is applied to the center of the positive electrode core body with respect to the width direction. Further, the positive electrode protective layer slurry is applied to both ends with respect to the width direction of the region coated with the positive electrode active material layer slurry.

The positive electrode core body coated with the positive electrode active material layer slurry and the positive electrode protective layer slurry is dried to remove NMP contained in the positive electrode active material layer slurry and the positive electrode protective layer slurry. Thus, a positive electrode active material layer and a protective layer are formed. After that, the positive electrode active material layer is compressed into a positive electrode original plate 400 by passing it between a pair of press rollers.

FIG. 3A is a plan view of the positive electrode original plate 400 fabricated by the aforementioned method. A positive electrode active material layer 4 b is formed on both sides of a strip-shaped positive electrode core body 4 a along the longitudinal direction of the positive electrode core body 4 a. In the positive electrode core body 4 a, a positive electrode protective layer 4 c is formed near both ends with respect to the width direction of the region where the positive electrode active material layer 4 b is formed. A positive electrode core body exposed portion 4 d is formed at both ends of the positive electrode original plate 400 with respect to the width direction of the positive electrode original plate 400 along the longitudinal direction. Note that the thickness of the positive electrode active material layer 4 b is preferably larger than the thickness of the positive electrode protective layer 4 c. The thickness of the positive electrode protective layer 4 c formed on one side of the positive electrode core body 4 a is preferably 10 to 100 more preferably 15 to 50 μm.

FIG. 3B is a plan view of the positive electrode original plate 401 with tabs already formed. Cutting the positive electrode core body exposed portion 4 d of the positive electrode original plate 400 into a predetermined shape leaves the positive electrode original plate 401 with tabs already formed. When the positive electrode original plate 400 is cut to form tabs, the positive electrode original plate 400 is preferably cut by irradiating energy rays such as laser beams.

It is preferable to use a continuous oscillation (CW) laser for laser cutting. The output of the laser is preferably 500 W to 1200 W, more preferably 550 W to 1000 W, and even more preferably 600 W to 1000 W. The scanning speed of the laser is preferably 100 mm/s to 5000 mm/s. However, this is not necessarily the case. Note that a pulsed laser may be used instead.

In the positive electrode original plate 401 with tabs already formed, there are a plurality of positive electrode tabs 40 at both ends of the positive electrode original plate 401 with respect to the width direction with tabs already formed. Each positive electrode tab 40 is composed of a positive electrode core body exposed portion 4 d. As shown in FIG. 3B, the positive electrode original plate 400 can be cut so that the positive electrode protective layer 4 c remains at the base of each positive electrode tab 40 and at sides of the positive electrode original plate 401 obtained between the adjacent positive electrode tabs 40 with tabs already formed.

FIG. 3C is a plan view of the positive electrode plate 4. First, the positive electrode original plate 401 with tabs already formed is cut at the central portion with respect to the width direction along the longitudinal direction of the positive electrode original plate 401 with tabs already formed. After that, the positive electrode original plate 401 with tabs already formed is cut at predetermined intervals in the longitudinal direction of the positive electrode original plate 401 with tabs already formed, thereby fabricating the positive electrode plate 4. The positive electrode original plate 401 with tabs already formed can be cut by laser cutting, cutting using a mold or a cutter, or the like. The positive electrode original plate 401 with tabs already formed is preferably cut by a mold or a cutter.

FIG. 4 is a cross-sectional view along line IV-IV in FIG. 3C. As shown in FIG. 4, the positive electrode plate 4 has an active material layer-free region 4 f that is not provided with the positive electrode active material layer 4 b on the positive electrode core body 4 a. In the active material layer-free region 4 f, a positive electrode protective layer 4 c is formed adjacent to the positive electrode active material layer 4 b. A first protrusion 4 x that protrudes from one side of the positive electrode core body 4 a (upper side in FIG. 4) in the direction of the thickness of the positive electrode core body 4 a (vertical direction in FIG. 4) is formed at the end of the active material layer-free region 4 f The first protrusion 4 x has a region uncovered by the positive electrode protective layer 4 c. The first protrusion 4 x is a part where the positive electrode core body 4 a is melted and solidified by laser cutting. The first protrusion 4 x is likely to occur on the side of the positive electrode core body 4 a irradiated with the laser beam during laser cutting. The protrusion height T1 of the first protrusion 4 x is smaller than the thickness T2 of the positive electrode protective layer 4 c. Such a configuration makes it possible to effectively prevent the first protrusion 4 x from coming into contact with the separator and damaging the separator. Hence, even if the first protrusion 4 x faces the negative electrode plate 5 with the separator therebetween, short circuits between the positive electrode plate 4 and the negative electrode plate 5 can be prevented more reliably.

Note that the protrusion height T1 of the first protrusion 4 x is preferably ⅔ or less, more preferably ⅓ or less of the thickness T2 of the positive electrode protective layer 4 c.

Note that the protrusion height T1 of the first protrusion 4 x is preferably ¼ or less of the thickness of the portion of the positive electrode core body 4 a where the positive electrode active material layers 4 b are formed on both sides. Thus, damage to the separator can be prevented more effectively.

The relationship between the protrusion height T1 of the first protrusion 4 x and the thickness T2 of the positive electrode protective layer 4 c can be adjusted by adjusting the laser output for laser-cutting the positive electrode original plate 400, the laser scanning speed, the thickness of the positive electrode protective layer 4 c, the thickness of the positive electrode core body 4 a, and the like. As the laser output increases, the protrusion height T1 of the first protrusion 4 x tends to increase. Also, as the laser scanning speed increases, the protrusion height T1 of the first protrusion 4 x tends to decrease.

At the end of the active material layer-free region 4 f on the other side (lower side in FIG. 4) that is the side opposite to the side on which the first protrusion 4 x is formed, no protrusion protruding from the other side in the direction of the thickness of the positive electrode core body 4 a is preferably formed. Alternatively, at the end of the active material layer-free region 4 f on the other side (lower side in FIG. 4) that is the side opposite to the side on which the first protrusion 4 x is formed, a second protrusion that protrudes from the other side in the direction of the thickness of the positive electrode core body 4 a is preferably formed but the protrusion height of the second protrusion is preferably smaller than that of the first protrusion 4 x. With such a configuration, short circuits between the positive electrode plate 4 and the negative electrode plate 5 can be prevented more effectively. Note that the protrusion height of the second protrusion is preferably ⅓ or less, more preferably ⅕ or less of the protrusion height of the first protrusion 4 x.

It should be noted that the first protrusion 4 x may be formed so that its protrusion height T1 changes along the end of the active material layer-free region 4 f, that is, along the side of the positive electrode plate 4 on which the positive electrode tab 40 is provided. With such a configuration, even if the positive electrode plate 4 is bent during the process for manufacturing the square secondary battery 20 or during use of the square secondary battery 20, the stress is concentrated on a part of the first protrusion 4 x and the first protrusion 4 x can be effectively prevented from detaching from the positive electrode core body 4 a. In other words, even if the positive electrode plate 4 is bent, the stress is released in the portion where the protrusion height T1 of the first protrusion 4 x is partially small, so that the first protrusion 4 x is less likely to be damaged than in the case where the protrusion height T1 of the first protrusion 4 x is uniform. Note that the protrusion height of the lowest point of the first protrusion 4 x is preferably ½ or less, more preferably ¼ or less of the protrusion height of the highest point of the first protrusion 4 x. The protrusion height T1 of the first protrusion 4 x can be changed, for example, by changing the laser output or the laser scanning speed for laser cutting.

[Negative Electrode Plate]

A method of manufacturing a negative electrode plate will now be explained.

[Preparation of Negative Electrode Active Material Layer Slurry]

Graphite as a negative electrode active material, styrene-butadiene rubber (SBR) and carboxymethyl cellulose (CMC) as a binder, and water as a dispersion medium are mixed so that the graphite:SBR:CMC mass ratio becomes 98:1:1, thereby preparing a negative electrode active material layer slurry.

[Formation of Negative Electrode Active Material Layer]

The negative electrode active material layer slurry prepared by the aforementioned method is applied to both sides of a 8-μm-thick copper foil as the negative electrode core body with a die coater.

The negative electrode core body coated with the negative electrode active material layer slurry is dried to remove the water contained in the negative electrode active material layer slurry. Thus, the negative electrode active material layer is formed. After that, the negative electrode active material layer is compressed into the negative electrode original plate 500 by passing it between the pair of press rollers.

FIG. 5A is a plan view of the negative electrode original plate 500 fabricated by the aforementioned method. Negative electrode active material layers 5 b are formed on both sides of a strip-shaped negative electrode core body 5 a along the longitudinal direction of the negative electrode core body 5 a. Negative electrode core body exposed portions 5 c are formed at both ends of the negative electrode original plate 500 with respect to the width direction along the longitudinal direction of the negative electrode original plate 500.

FIG. 5B is a plan view of a negative electrode original plate 501 with tabs already formed. The negative electrode original plate 501 with tabs already formed is fabricated by cutting the negative electrode core body exposed portion 5 c of the negative electrode original plate 501 with tabs already formed, into a predetermined shape. The negative electrode original plate 500 can be cut by irradiation with energy rays such as lasers, a mold, a cutter, or the like. As for the negative electrode original plate 501 with tabs already formed, a plurality of negative electrode tabs 50 are formed at both ends with respect to the width direction of the negative electrode original plate 501 with tabs already formed. Note that each negative electrode tabs 50 consists of a negative electrode core body exposed portion 5 c. The negative electrode original plate 500 is preferably cut by irradiation with energy rays to form the negative electrode tabs 50.

FIG. 5C is a plan view of the negative electrode plate 5. First, the negative electrode original plate 501 with tabs already formed is cut at the central portion with respect to the width direction along the longitudinal direction of the negative electrode original plate 501 with tabs already formed. After that, the negative electrode original plate 501 with tabs already formed is cut at predetermined intervals in the longitudinal direction of the negative electrode original plate 501 with tabs already formed, thereby fabricating the negative electrode plate 5.

[Fabrication of Electrode Assembly]

The positive electrode plate 4 and the negative electrode plate 5 fabricated by the aforementioned method are laminated with a separator therebetween, thereby manufacturing a laminated electrode assembly 3. FIG. 6 is a plan view of the electrode assembly 3. A positive electrode tab group 40A of positive electrode tabs 40 and a negative electrode tab group 50A of negative electrode tabs 50 are provided at one end of the electrode assembly 3.

Note that the area of the region of the positive electrode plate 4 in which the positive electrode active material layer 4 b is formed in a plan view is preferably smaller than the area of the region of the negative electrode plate 5 in which the negative electrode active material layer 5 b is formed in a plan view. In a plan view of the electrode assembly 3, all the regions of the positive electrode plate 4 in which the positive electrode active material layer 4 b is formed are preferably located in the regions of the negative electrode plate 5 where the negative electrode active material layer 5 b is formed. It is preferable to use a porous film of polyolefin as the separator. It is more preferable to use a separator in which a heat-resistant layer containing ceramic is formed on the surface of the porous film of polyolefin.

[Connection Between Current Collector and Tabs]

As shown in FIG. 7, the positive electrode tab groups 40A of the two electrode assemblies 3 are connected to the second positive electrode current collector 6 b, and the negative electrode tab groups 50A of the two electrode assemblies 3 are connected to the second negative electrode current collector 8 b. The positive electrode tab groups 40A are welded and joined to the second positive electrode current collector 6 b, thereby forming a welded connection portion 60. The negative electrode tab groups 50A are welded and joined to the second negative electrode current collector 8 b, thereby forming a welded connection portion 61.

A thin portion 6 c is formed in the second positive electrode current collector 6 b, and a current collector opening 6 d is formed in the thin portion 6 c. In the thin portion 6 c, the second positive electrode current collector 6 b is connected to the first positive electrode current collector 6 a. In the second positive electrode current collector 6 b, a current collector through hole 6 e is formed in a position facing the electrolytic solution injection hole 15 of the sealing plate 2.

A thin portion 8 c is formed in the second negative electrode current collector 8 b, and a current collector opening 8 d is formed in the thin portion 8 c. In the thin portion 8 c, the second negative electrode current collector 8 b is connected to the first negative electrode current collector 8 a.

A connection between the positive electrode tab group 40A and the second positive electrode current collector 6 b, and a connection between the negative electrode tab group 50A and the second negative electrode current collector 8 b can be achieved by ultrasonic welding, resistance welding, laser welding, or the like.

[Mounting of Components to Sealing Plate]

FIG. 8 is a diagram showing the inner side of the battery of the sealing plate 2 mounted with the components. Each component is mounted to the sealing plate 2 in the following manner.

An external insulating member 10 is located on the outer side of the battery around the positive electrode terminal insertion hole 2 a of the sealing plate 2. An internal insulating member 11 and a first positive electrode current collector 6 a are located on the inner side of the battery around the positive electrode terminal insertion hole 2 a of the sealing plate 2. After that, the positive electrode terminal 7 is inserted from the outside of the battery into the through hole of the external insulating member 10, the positive electrode terminal insertion hole 2 a of the sealing plate 2, the through hole of the internal insulating member 11, and the through hole of the first positive electrode current collector 6 a, and the end of the positive electrode terminal 7 is crimped onto the first positive electrode current collector 6 a. Hence, the positive electrode terminal 7 and the first positive electrode current collector 6 a are fixed to the sealing plate 2. Note that the crimped portion of the positive electrode terminal 7 and the first positive electrode current collector 6 a are preferably connected by welding.

An external insulating member 12 is located on the outer side of the battery around the negative electrode terminal insertion hole 2 b of the sealing plate 2. An internal insulating member 13 and a first negative electrode current collector 8 a are located on the inner side of the battery around the negative electrode terminal insertion hole 2 b of the sealing plate 2. After that, the negative electrode terminal 9 is inserted from the outside of the battery into the through hole of the external insulating member 12, the negative electrode terminal insertion hole 2 b of the sealing plate 2, the through hole of the internal insulating member 13, and the through hole of the first negative electrode current collector 8 a, and the end of the negative electrode terminal 9 is crimped onto the first negative electrode current collector 8 a. Hence, the negative electrode terminal 9 and the first negative electrode current collector 8 a are fixed to the sealing plate 2. Note that the crimped portion of the negative electrode terminal 9 and the first negative electrode current collector 8 a are preferably connected by welding.

In the internal insulating member 11, a solution injection opening 11 a is provided in a portion facing the electrolytic solution injection hole 15 provided in the sealing plate 2. A tubular part 11 b is provided at the edge of the solution injection opening 11 a.

[Connection Between First Current Collector and Second Current Collector]

FIG. 9 shows the inside of the battery of the sealing plate 2 after the second positive electrode current collector 6 b is mounted to the first positive electrode current collector 6 a and the second negative electrode current collector 8 b is mounted to the first negative electrode current collector 8 a.

The second positive electrode current collector 6 b to which the positive electrode tab group 40A is connected is located on the internal insulating member 11 so that a part thereof overlaps with the first positive electrode current collector 6 a. The thin portion 6 c is irradiated with a laser beam, so that the second positive electrode current collector 6 b and the first positive electrode current collector 6 a are connected by welding, thereby forming a welded connection portion 62. The second negative electrode current collector 8 b to which the negative electrode tab group 50A is connected is located on the internal insulating member 13 so that a part thereof overlaps with the first negative electrode current collector 8 a. The thin portion 8 c is irradiated with a laser beam, so that the second negative electrode current collector 8 b and the first negative electrode current collector 8 a are connected by welding, thereby forming a welded connection portion 63.

[Fabrication of Secondary Battery]

Two positive electrode tab groups 40A and two negative electrode tab groups 50A are curved so that the upper side of one electrode assembly 3 in FIG. 9 (the side further to the viewer in FIG. 9) and the upper side of the other electrode assembly 3 (the side closer to the viewer in FIG. 9) cone into contact with each other directly or via another member. As a result, the two electrode assemblies 3 are combined into one unit. The two electrode assemblies 3 are located in an electrode assembly holder 14 consisting of a box-shaped or a bag-shaped insulating sheet.

One positive electrode tab group 40A and the other positive electrode tab group 40A are curved in different directions. One negative electrode tab group 50A and the other negative electrode tab group 50A are curved in different directions.

The two electrode assemblies 3 wrapped in the electrode assembly holder 14 are inserted into the square exterior body 1. The sealing plate 2 and the square exterior body 1 are then welded to seal the opening of the square exterior body 1 with the sealing plate 2. The electrolytic solution is then injected into the square exterior body 1 through the electrolytic solution injection hole 15 provided in the sealing plate 2. After that, the electrolytic solution injection hole 15 is sealed with a sealing member 16 such as a blind rivet. Thus, the square secondary battery 20 is completed.

The protective layer provided on the electrode plate is preferably a layer having lower electrical conductivity than the core body constituting the electrode plate. The protective layer is preferably a layer having lower electrical conductivity than the active material layer. Although the aforementioned embodiment showed the example in which the protective layer is provided on the positive electrode plate, the protective layer may be provided on the negative electrode plate instead.

The protective layer preferably contains a ceramic and a binder. The ceramic may be an oxide, nitride, boride, carbide, silicide, sulfide or the like. The ceramic may be aluminum oxide, boehmite, titanium oxide, silicon oxide, tungsten oxide, or the like. However, this is not necessarily the case. The binder is preferably a resin-based binder. However, this is not necessarily the case. Note that the protective layer does not necessarily contain a ceramic. For example, the protective layer may be a resin layer. The protective layer may be made of a conductive material of a carbon material or the like. Note that the protective layer does not necessarily contain a conductive material.

The thickness of the protective layer is preferably 10 to 100 μm, more preferably 15 to 50 μm.

The positive electrode core body is preferably made of aluminum or an aluminum alloy containing aluminum as a main component. Note that the aluminum alloy is preferably an aluminum alloy with an aluminum content of 90 mass % or more, more preferably an aluminum alloy with an aluminum content of 95 mass % or more.

The negative electrode core body is preferably made of copper or a copper alloy containing copper as a main component. Note that the copper alloy is preferably a copper alloy with a copper content of 95 mass % or more, more preferably a copper alloy with a copper content of 99 mass % or more.

The thickness of the core body is preferably 5 to 30 μm, more preferably 5 to 20 μm.

Although the aforementioned embodiment showed the example in which two electrode assemblies are located in the battery case, one or three or more electrode assemblies may be used. The electrode assemblies may be laminated electrode assemblies or wound electrode assemblies.

The details of the configuration of the end portion of the active material layer-free region have been described for the positive electrode plate in the aforementioned embodiment, and the same configuration can be applied to the negative electrode plate.

Although the example in which the positive electrode current collector and the negative electrode current collector are each composed of two parts has been described in the aforementioned embodiment, the positive electrode current collector and the negative electrode current collector may each be composed of one part.

Known materials can be used for the positive electrode plate, the negative electrode plate, the separator, the electrolyte, and the like.

REFERENCE SIGNS LIST

-   20 square secondary battery -   1 square exterior body -   2 sealing plate -   2 a positive electrode terminal insertion hole -   2 b negative electrode terminal insertion hole -   100 battery case -   3 electrode assembly -   4 positive electrode plate -   4 a positive electrode core body -   4 b positive electrode active material layer -   4 c positive electrode protective layer -   4 d positive electrode core body exposed portion -   4 f active material layer-free region -   4 x first protrusion -   40 positive electrode tab -   40A positive electrode tab group -   400 positive electrode original plate -   401 positive electrode original plate with tabs already formed -   5 negative electrode plate -   5 a negative electrode core body -   5 b negative electrode active material layer -   5 c negative electrode core body exposed portion -   50 negative electrode tab -   50A negative electrode tab group -   6 positive electrode current collector -   6 a first positive electrode current collector -   6 b second positive electrode current collector -   6 c thin portion -   6 d current collector opening -   6 e current collector through hole -   7 positive electrode terminal -   8 negative electrode current collector -   8 a first negative electrode current collector -   8 b second negative electrode current collector -   8 c thin portion -   8 d current collector opening -   9 negative electrode terminal -   10 external insulating member -   11 internal insulating member -   11 a solution injection opening -   11 b tubular part -   12 external insulating member -   13 internal insulating member -   14 electrode assembly holder -   15 electrolytic solution injection hole -   16 sealed member -   17 gas discharge valve -   60, 61, 62, 63 welded connection portion 

1. A secondary battery electrode plate having a metal core body and an active material layer on both sides of the core body, wherein the core body has an active material layer-free region in which the active material layer is not formed on a surface of the core body, a first protrusion that protrudes from one side of the core body in the direction of the thickness of the core body is formed at an end of the active material layer-free region, on the one side of the core body of the active material layer-free region, a protective layer is formed in a portion adjacent to the active material layer, and the protrusion height of the first protrusion is smaller than the thickness of the protective layer.
 2. The secondary battery electrode plate according to claim 1, wherein the protrusion height of the first protrusion is ¼ or less of the thickness of a portion of the core body, the portion having the active material layer on both sides.
 3. The secondary battery electrode plate according to claim 1, wherein at an end of the active material layer-free region, on the other side being the side opposite to the side on which the first protrusion is formed, no protrusion protruding from the other side in the direction of the thickness of the core body is formed or a second protrusion having a protrusion height smaller than the protrusion height of the first protrusion is formed.
 4. The secondary battery electrode plate according to claim 1, wherein the first protrusion is formed along the end of the active material layer-free region, and the protrusion height of the first protrusion changes along the end of the active material layer-free region.
 5. The secondary battery electrode plate according to claim 4, wherein the protrusion height of the highest point of the first protrusion is at least five times the protrusion height of the lowest point of the first protrusion.
 6. The secondary battery electrode plate according to claim 1, wherein the core body is made of aluminum or an aluminum alloy.
 7. A secondary battery comprising: the electrode plate according to claim 1; and another electrode plate having a polarity different from that of the electrode plate. 